Ruthenium-cobalt nanoalloys encapsulated in nitrogen-doped graphene as active electrocatalysts for producing hydrogen in alkaline media

نویسندگان

  • Jianwei Su
  • Yang Yang
  • Guoliang Xia
  • Jitang Chen
  • Peng Jiang
  • Qianwang Chen
چکیده

The scalable production of hydrogen could conveniently be realized by alkaline water electrolysis. Currently, the major challenge confronting hydrogen evolution reaction (HER) is lacking inexpensive alternatives to platinum-based electrocatalysts. Here we report a high-efficient and stable electrocatalyst composed of ruthenium and cobalt bimetallic nanoalloy encapsulated in nitrogen-doped graphene layers. The catalysts display remarkable performance with low overpotentials of only 28 and 218 mV at 10 and 100 mA cm-2, respectively, and excellent stability of 10,000 cycles. Ruthenium is the cheapest platinum-group metal and its amount in the catalyst is only 3.58 wt.%, showing the catalyst high activity at a very competitive price. Density functional theory calculations reveal that the introduction of ruthenium atoms into cobalt core can improve the efficiency of electron transfer from alloy core to graphene shell, beneficial for enhancing carbon-hydrogen bond, thereby lowing ΔGH* of HER.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Preparation of Nitrogen-Doped Graphene By Solvothermal Process as Supporting Material for Fuel Cell Catalysts

Development of efficient electrocatalysts for oxygen reduction reaction (ORR) is one of the most important issues for optimizing the performance of fuel cells and metal-air batteries. The introduction of nitrogen into carbon nanostructures has created new pathways for the development of non-precious electrocatalysts in fuel cells. In this work, nitrogen-doped graphene (NG) was synthesized by a ...

متن کامل

Facile Synthesis of N, S-Doped Graphene from Sulfur Trioxide Pyridine Precursor for the Oxygen Reduction Reaction

In the work presented here, nitrogen and sulfur co doped on porous graphene was synthesized using pyrolysis at 900°C for 2h and the hydrothermal technique at 180°C for 24h as metal-free electrocatalysts for oxygen reduction reaction (ORR) under alkaline conditions. All the materials have been characterized by Scanning Electron Microscopy (SEM) and X-ray photo-electron spectroscopy (XPS). Moreov...

متن کامل

Hydrothermal synthesis of nitrogen doped graphene supported cobalt ferrite (NG@CoFe2O4) as photocatalyst for the methylene blue dye degradation

A magnetic NG@CoFe2O4 photocatalyst was developed via a facile hydrothermal method and characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and vibrating sample magnetometry (VSM) techniques. The CoFe2O4 nanoparticles were found to have a size between 100-150 nm and were unifo...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 8  شماره 

صفحات  -

تاریخ انتشار 2017